Abstract

The use of enzyme additives in anaerobic digestion facilities has increased in recent years. According to the manufacturers, these additives should increase or accelerate the biogas yield and reduce the viscosity of the digester slurry. Such effects were confirmed under laboratory conditions. However, it has not yet been possible to quantify these effects in practice, partly because valid measurements on large-scale plants are expensive and challenging. In this research, a new enzyme product was tested under full-scale conditions. Two digesters were operated at identic process parameters—one digester was treated with an enzyme additive and a second digester was used as reference. A pipe viscometer was designed, constructed and calibrated and the rheological properties of the digester slurry were measured. Non-Newtonian flow behavior was modelled by using the Ostwald–de Baer law. Additionally, the specific biomethane yield of the feedstock was monitored to assess the influence of the enzyme additive on the substrate degradation efficiency. The viscosity measurements revealed a clear effect of the added enzyme product. The consistency factor K was significantly reduced after the enzyme application. There was no observable effect of enzyme application on the substrate degradation efficiency or specific biomethane yield.

Highlights

  • Anaerobic digestion (AD) is an established technology to gain energy from biogenic materials, agricultural residues and biowaste

  • Two digesters were operated at identic process parameters—one digester was treated with an enzyme additive and a second digester was used as reference

  • The application of C1 enzymes started at day 120 in digester 3.1, whilst digester 3.2 was used as reference—i.e., with the same process conditions (same substrate and organic loading Rate (OLR)) but without enzyme application

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Summary

Introduction

Anaerobic digestion (AD) is an established technology to gain energy from biogenic materials, agricultural residues and biowaste. By end of 2016, there were approximately 8700 biogas plants in operation in Germany [1], and the total number in Europe exceeds 18,200 [2]. The majority of biogas digesters currently operating in Europe are designed as continuously stirred tank reactors (CSTR). This reactor type requires more or less permanent homogenization and is equipped with agitators. A broad variety of mixer types and mixing techniques have been developed and implemented, depending on the reactor size, feedstock and operation procedure. Mixing is still an issue and technical problems with mixers and stirrers came second in a survey of technical problems at biogas facilities in Germany [3,4]

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