Influence of Doping-Ion-Type on the Characteristics of Al2O3-Based Nanocomposites and Their Capabilities of Removing Indigo Carmine from Water

Abstract

Globally, the continuous contamination of natural water resources is a severe issue, and looking for a solution for such a massive problem should be the researcher’s concern. Herein, Al2O3, Al2O3-CuO, Al2O3-NiO, and Al2O3-CoO were prepared via a simple and fast route, utilizing glucose as a capping material. All synthesis conditions were uniform to make the fabricated nanomaterials’ characteristics exclusively influenced by only the ion type. The SEM analysis showed that the particles of the synthesized Al2O3, Al2O3-CuO, Al2O3-NiO, and Al2O3-CoO were all less than 25 nm. The Al2O3-NiO showed the smallest particle size (11 to 14 nm) and the best BET surface area of 125.6 m2 g−1. All sorbents were tested for removing organic pollutants, as exemplified by indigo carmine (IGC) dye. The Al2O3-NiO possessed the highest adsorption capacity among the other sorbents for which it had been selected for further investigations. The IGC sorption reached equilibrium within 2.0 h, and the kinetic study revealed that the IGC removal by Al2O3-NiO nanocomposite fitted the FOM and the LFM. The sorbent showed an experimental adsorption capacity (qt) of 456.3 mg g−1 from a 200 mg L−1 IGC solution and followed the Langmuir model. The thermodynamic findings indicated an endothermic, spontaneous, and physisorption nature. The seawater and groundwater samples contaminated with 5.0 mg L−1 IGC concentrations were fully remediated using the Al2O3-NiO nanocomposite. The reuse study showed 93.3% average efficiency during four successive cycles. Consequently, prepared Al2O3-NiO nanocomposite is recommended for the treatment of contaminated water.