Abstract

The microstructure and electrical properties of ZnOBi2O3–MnO2-based varistor ceramics doped with different Cr2O3 content were investigated. The addition of Cr2O3 caused a transformation of minor secondary phases from Bi7.72Mn0.28O12.14 to Bi2O3 dissolving different amount of Cr. The average grain size of sample with 0.2mol% Cr2O3 increased remarkably from a range of 6.38–6.62μm to 9.79μm, and the barrier voltage decreased to 1.31V. With the increase of Cr2O3, the nonlinear coefficients of sintered samples decreased to 25.0 at 0.2mol%, and then it further increased up to 40.0, a comparable value with the one of the undoped sample, at 0.8mol%. The results showed small amounts of Cr2O3 promote the grain-growth at a relatively low sintering temperature, and thus result in the shift of breakdown voltages to a lower value.

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