Abstract

The influence of sulphur, copper, manganese, phosphorus, carbon, aluminium, antimony and nickel additives on the crystallization and Curie points of amorphous Fe 80B 14Si 6 alloy was studied by scanning calorimetry and by thermogravimetry. The onset of crystallization in amorphous Fe14at.%B6at.%Si alloys without and with 0.38 at.% CU was studied by means of transmission electron microscopy. A two-step crystallization reaction was observed. The copper addition decreases the onset temperature of the first step of crystallization but has essentially no effect on the second. Magnetic measurements corroborate the observed crystallization behaviour.

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