Influence of Conductive Additives and Binder on the Impedance of Lithium-Ion Battery Electrodes: Effect of Morphology

Simon Hein,Timo Danner,Volker Schmidt,Arnulf Latz,Benedikt Prifling,Ingo Manke,Markus Osenberg,André Hilger,Daniel Westhoff,Margret Wohlfahrt-Mehrens,Rares Scurtu,Alice Hoffmann,Lea Kremer

doi:10.1149/1945-7111/ab6b1d

Abstract

Most cathode materials for lithium-ion batteries exhibit a low electronic conductivity. Hence, a significant amount of conductive graphitic additives are introduced during electrode production. The mechanical stability and electronic connection of the electrode is enhanced by a mixed phase formed by the carbon and binder materials. However, this mixed phase, the carbon binder domain (CBD), hinders the transport of lithium ions through the electrolyte pore network. Thus, reducing the performance at higher currents. In this work we combine microstructure resolved simulations with impedance measurements on symmetrical cells to identify the influence of the CBD distribution. Microstructures of NMC622 electrodes are obtained through synchrotron X-ray tomography. Resolving the CBD using tomography techniques is challenging. Therefore, three different CBD distributions are incorporated via a structure generator. We present results of microstructure resolved impedance spectroscopy and lithiation simulations, which reproduce the experimental results of impedance spectroscopy and galvanostatic lithiation measurements, thus, providing a link between the spatial CBD distribution, electrode impedance, and half-cell performance. The results demonstrate the significance of the CBD distribution and enable predictive simulations for battery design. The accumulation of CBD at contact points between particles is identified as the most likely configuration in the electrodes under consideration.

Highlights

Influence of Conductive Additives and Binder on the Impedance of Lithium-Ion Battery Electrodes: Effect of Morphology
The Scanning Electron Microscopy (SEM) cross-cut shown in Fig. 1a suggests that the conductive additive and binder domain (CBD) has a quite dense morphology and is mainly located at the contact points of the NMC particles
Our studies demonstrate that the distribution of passive materials is very important for the operation of the battery

Summary

OPEN ACCESS

Influence of Conductive Additives and Binder on the Impedance of Lithium-Ion Battery Electrodes: Effect of Morphology. To cite this article: Simon Hein et al 2020 J. Soc. 167 013546 View the article online for updates and enhancements. This content was downloaded from IP address 129.13.72.197 on 15/01/2021 at 10:47. Simon Hein,1,2,z Timo Danner,1,2,* Daniel Westhoff,[3] Benedikt Prifling,[3] Rares Scurtu,[4] Lea Kremer,4,** Alice Hoffmann,[4] André Hilger,[5] Markus Osenberg,[5] Ingo Manke,[5] Margret Wohlfahrt-Mehrens,4,* Volker Schmidt,[3] and Arnulf Latz1,2,6,*.

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Results and Discussion

Conclusions