Abstract

The effect of cobalt substitution on structure, magnetic behaviour, magnetic arrangement, and hyperfine interactions in (Fe1−xCox)76Mo8Cu1B15 (x = 0, 0.1, 0.2, 0.25, 0.5) is studied by the Mossbauer spectrometry for both as-quenched and annealed alloys. Partial substitution of Fe by Co resulted in an enhancement of the average value of hyperfine magnetic field distributions as a function of x probably due to higher magnetic moment of Co. After annealing, a two-phase nanocrystalline structure composed of amorphous matrix and bcc-FeCo nanocrystallites was observed. Mossbauer spectra were fitted with up to four six-line patterns of narrow lines assigned to different number of Co nearest neighbours inside a bcc-FeCo lattice.

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