Abstract

Coal due to its relatively large quantities and wide distribution worldwide has generated renewed interest in research and development with the aim of establishing coal conversion technologies that are technically reliable, environmentally and economically feasible. It has proved to be a prominent energy source in emerging markets with increasing energy demand by accounting for the largest increase in the demand of energy amongst all other energy sources. Furthermore, with its higher mesophase content, coal tar is an appropriate raw material for precursors in the production of carbon fiber. However, whenever a material is put to use, it is important to be able to associate its properties to the behavioral characteristics during a conversion process so as to have a basis for opting for the material in a given process or adjusting the operating conditions in order to optimize the material utilization. Therefore, as with any other material, it is important to be able to relate the properties of coal to its utilization. A review was carried out on the influence of coal properties on four main utilization technologies: gasification, carbonization, liquefaction and carbon fibre production. Among several properties rank, type, mineral matter content, distribution of trace elements, structural composition and pore structure were found to be most influential on the behavior of coal during conversion processes.

Highlights

  • IntroductionCoal is a combustible sedimentary rock formed from ancient vegetation which has been compressed between other rock strata

  • Whenever a material is put to use, it is important to be able to associate its properties to the behavioral characteristics during a conversion process so as to have a basis for opting for the material in a given process or adjusting the operating conditions in order to optimize the material utilization

  • Type, mineral matter content, distribution of trace elements, structural composition and pore structure were found to be most influential on the behavior of coal during conversion processes

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Summary

Introduction

Coal is a combustible sedimentary rock formed from ancient vegetation which has been compressed between other rock strata. The vegetation was accumulated under conditions that either limited or inhibited its decay. It is a rock with one evolution process, it is very heterogeneous in nature and the heterogeneity is brought about by the kind of vegetation deposited (coal type), degree of coalification (coal rank) and range of impurities (coal grade) (Edgar 1983; Warwick 2002; Suarez-Ruiz and Crelling 2008). The rank, type and grade are highly

C Lignite
Carbonization
Organic composition
Chemical composition
Inorganic composition
Mineral matter content
Coal grindability and handleability
Carbon fibre production
Chemical structural composition
Method
Result
Both produced carbon fibers with uniform morphology and clear surfaces
Addition of CTP to PAN decreased electrical conductivity and resistivity
CF from bituminous coal tar pitch had higher tensile strength
Investigate the process optimization techniques
Molecular weight distribution
Fluidity
Coal gasification
Coal reactivity
Properties of ash and slag (1) Mineral matter conversion into ash
Coal particle size
Coal caking and swelling
Liquefaction
Degree of coalification
More tar and oil can be distilled from coals with high volatile matter
Bright coals are best for liquefaction than splint coals
Pyrite in coal tends to subject catalytic effect on coal hydrogenation
Size of coal particle
Inorganic matter
Discussion
Findings
Summary and Conclusion

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