Influence of coal petrology on methane adsorption capacity of the Middle Jurassic coal in the Yuqia Coalfield, northern Qaidam Basin, China

Abstract

The lower coalbed methane (CBM) adsorption capacity of the low rank coals is not only related to its lower maturity, but also determined by the coal maceral compositions. In this study, a total of 13 samples including 10 coals and 3 carbonaceous mudstones, were collected from the Middle Jurassic Dameigou Formation in the borehole YQ-1 of the Yuqia Coalfield, northern Qaidam Basin, NW China. Coal lithotypes, maceral compositions, coal ranks, coal facies and methane adsorption characteristics of these samples were investigated using microscopic observation, proximate analysis, porosity analysis, and isothermal adsorption experiments. The results show that the maceral composition has a great influence on the methane adsorption capacity, and the influence of vitrinite on the methane adsorption is generally stronger than that of inertinite at a similar coal rank. For most samples, there is a positive correlation between the vitrinite contents and the Langmuir volume (VL), a negative correlation between the inertinite contents and the VL, and no obvious correlation between the exinite contents and the VL. Furthermore, the vitrinite/inertinite (V/I) ratio also shows a positive relationship with the VL. However, some samples containing large amounts of unfilled fusinite and/or semifusinite have more pore spaces favoring methane adsorption and can also adsorb significant quantities of methane. Consequently, coals with higher vitrinite contents, in association with some unfilled fusinites or semifusinites, should have the greatest adsorption capacity. Coal maceral compositions vary with the types of coal facies, and thus the methane adsorption capacity of coals may be closely related to coal facies. It is found that the methane adsorption capacities of the coals in a wet forest swamp (Type I) and an intergradation forest swamp (Type II) are greater than those in a drained forest swamp (Type III) and an open water peat swamp (Type IV). It is suggested that the area developed with the wet forest swamp and in the intergradation forest swamp with high porosity should be the best target areas for the CBM exploration in the Yuqia Coalfield.