Influence of chemistry and surface roughness of various thermal barrier coatings on the wettability of molten sand

Abstract

High temperature wettability experiments were carried out to investigate how chemistry and surface roughness affect wetting characteristics of molten sand several promising thermal/environmental barrier coatings. Contact angle experiments were performed on varying as-sprayed and polished yttria-stabilized zirconia (YSZ), rare-earth oxide-YSZ (REO-YSZ), and rare-earth silicate coatings subjected to molten synthetic sand at 1260 °C. The results showed that the spreading rate of molten sand was higher on silicate-based environmental barrier coatings (~60°/min) than on Zr-based thermal barrier coatings (~25°/min). Increased surface roughness had opposite effects on the wettability depending on the reactivity of the coatings. Wettability decreased on coatings such as YSZ (which did not react with sand) but increased for REO-YSZ coatings (which formed reaction products with sand). It was found that while the REO-YSZ coatings were able to promote formation of the apatite that performed as a sealing layer to reduce further infiltration, molten sand wetting increased. YSZ was found to have greater wetting resistance in the roughened state while the REO-YSZ coatings had greater wetting resistance in the polished state. Surface energy, microstructure, and molten sand penetration also play a key role in the wetting kinetics and are discussed. This work reveals the dependency of chemistry and surface roughness on influencing the “sandphobicity” (analogous to hydrophobicity) of a material and provides insights for optimizing these variables to realize more “sandphobic” coatings.