Abstract
Pt(II) and Pd(II) complexes (1 and 2, respectively) with thiomorpholine-4-carbonitrile (TM-CN), an N-substituted thiomorpholine derivative, were synthesized from tetrachlorido precursors in water. ...
Highlights
Influence of C‒H/X (X = S, Cl, N, Pt/Pd) interactions on the molecular and crystal structures of Pt(II) and Pd(II) complexes with thiomorpholine-4-carbonitrile: crystallographic, thermal and DFT study
Labelling of atoms used for NMR signal assignments. 2
C-H/M interactions obtained from the periodic calculations of axial and equatorially coordinated Pd and Pt
Summary
Influence of C‒H/X (X = S, Cl, N, Pt/Pd) interactions on the molecular and crystal structures of Pt(II) and Pd(II) complexes with thiomorpholine-4-carbonitrile: crystallographic, thermal and DFT study. A University of Belgrade - Faculty of Chemistry, Studentski trg 12-16, 11000 Belgrade, Serbia bInstitute of Technical Sciences of the Serbian Academy of Sciences and Arts, Knez Mihailova 35/IV, 11000 Belgrade, Serbia cInstitute of Chemistry, Metallurgy and Technology, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia dDepartment of Chemistry, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 4, 21000 Novi Sad, Serbia eFaculty of Mining and Geology, University of Belgrade, Đušina 5, 11000 Belgrade, Serbia fUniversité de Strasbourg, Université de Haute-Alsace, CNRS, LIMA – UMR 7042, ECPM, 67000 Strasbourg, France gUniversité de Strasbourg, CNRS, LIT – UMR 7200, Faculty of Pharmacy, 67000 Strasbourg, France hFaculty of Chemistry, University of Gdansk, Wita Stwosza 63, PL80-308 Gdansk, Poland i University of Belgrade - Faculty of Agriculture, Nemanjina 6, 11000 Belgrade, Serbia
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