Influence of Biomass Burning on the Levels of Atmospheric Polycyclic Aromatic Hydrocarbons and Their Nitro Derivatives in Chiang Mai, Thailand

Thanyarat Chuesaard,Kazuichi Hayakawa,Takayuki Kameda,Akira Toriba,Thaneeya Chetiyanukornkul

doi:10.4209/aaqr.2013.05.0161

Thanyarat Chuesaard, Kazuichi Hayakawa + Show 3 more

Open Access

https://doi.org/10.4209/aaqr.2013.05.0161

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Abstract

ABSTRACTChiang Mai and several other provinces in northern Thailand have been annually facing air pollution problems during the dry season. Ten polycyclic aromatic hydrocarbons (PAHs); 19 nitropolycyclic aromatic hydrocarbons (NPAHs); and levoglucosan (LG), a marker for biomass burning, were quantified in total suspended particulates (TSP) collected in Chiang Mai during the dry, transition, and wet seasons in 2010. The concentrations of PAHs and NPAHs in the dry season were significantly higher than in the wet season. The [Benzo[a]pyrene (BaP)] – [benzo[ghi]perylene (BghiPe)] ratio, as an indicator of traffic, and the correlations of PAHs and NPAHs with LG showed that biomass burning significantly contributes to air pollution in the dry season. 9-Nitroanthracene (9-NA) was the most abundant NPAH which suggests that 9-NA is generated from biomass burning. We proposed the [9-NA] – [1-nitropyrene (1-NP)] ratio as a new indicator for assessing the contribution of biomass burning. Biomass burning was a major source of PAHs and NPAHs in the dry season, whereas vehicle exhaust was the main contribution in the wet season. The high carcinogenic risks in the dry season correlate with more harmful air conditions during this season. Thus, it is important to control biomass burning to reduce air-pollution-related health risks during the dry season in northern Thailand.

Highlights

The increase in fossil fuel consumption, along with the rapid development of industrial and financial activities in Southeast Asia, has caused serious air pollution problems in cities such as Bangkok, Hanoi, Kuala Lumpur, and Singapore (He et al, 2010)
The [Benzo[a]pyrene (BaP)] – [benzo[ghi]perylene (BghiPe)] ratio, as an indicator of traffic, and the correlations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) with LG showed that biomass burning significantly contributes to air pollution in the dry season. 9-Nitroanthracene (9-NA) was the most abundant NPAH which suggests that 9-NA is generated from biomass burning
Biomass burning was a major source of PAHs and NPAHs in the dry season, whereas vehicle exhaust was the main contribution in the wet season

Summary

Introduction

The increase in fossil fuel consumption, along with the rapid development of industrial and financial activities in Southeast Asia, has caused serious air pollution problems in cities such as Bangkok, Hanoi, Kuala Lumpur, and Singapore (He et al, 2010). Biomass burning (agricultural burning and forest fires) in Southeast Asia produces high levels of haze, especially in the dry season (Reid et al, 2013). Northern Thailand faces haze-related health threats from February to April every year (Chantara, 2012). The highest incidence of lung cancer has been recognized in this region of Thailand (Wiwatanadate, 2011). Chiang Mai (18°47'N and 98°59'E) is the largest. PM contains many inorganic and organic species, many of which can adversely affect human health. Polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) are of great concern

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