Influence of annealing in oxygen and argon on the superconducting properties of Li-doped YBCO single-grain bulks

Abstract

YBa2(Cu1-xLix)3O7-δ single-grain bulk superconductors with different Li concentrations were grown using the top-seeded melt growth process. Structural analysis of the samples and magnetisation measurements showed that substitution of the Cu atoms by the Li atoms took place in the YBa2Cu3O7-δ crystal lattice. This substitution was accompanied by the formation of effective pinning centres, which improved the pinning properties of the samples and increased the critical current density. Additional annealing and reannealing in oxygen and argon showed that the superconducting transition temperature displays substantially more suppression, when the Li-doped YBa2Cu3O7-δ samples were annealed in argon, that was associated with different distribution of the Li atoms between the CuO chains and the CuO2 planes in comparison to annealing in oxygen. Investigation of the critical current densities showed that the pinning properties of YBa2(Cu1-xLix)3O7-δ single-grain bulk superconductors did not depend on the arrangement of the Li atoms in the YBa2Cu3O7-δ crystal lattice. It was also observed that the crystal lattice parameters and the mean diameter of the non-superconducting Y2BaCuO5 particles systematically change with Li concentration.