Abstract

The influence of annealing in N 2 atmosphere on the superconductivity and normal states of a series Bi-system 2223 phase samples with high quality were studied by x-ray diffraction, thermal analysis and resistivity determination. It was discovered as the annealing time was increased, the critical temperature of the sample increased and the resistivity decreased. There was an optimum time for annealing. As the annealing time was longer than this optimum time, the converse result was obtained, namely, the increase in annealing time made the Tc decrease and resistivity increase. The experiment also showed that this effect was reversible. The Tc was suppressed by longer annealing time in N 2, but constrictive annealing in O 2, the original state could be recovered. The difference between these and some former results is discussed. Analyzing the results carefully, the relationship between Tc and resistivity, then the Tc and carrier concentration is well established.

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