Abstract

Anharmonic parameters of the Buckingham type potential function have been computed at 0 °K for solid argon, krypton and xenon. The contribution of cubic and quartic terms of potential energy expansion to Helmholtz free energy has been taken into account by an iteration method. The results are compared with quasiharmonic parameters of the same potential. The effect of anharmonicity is found to be negligible in the case of krypton and xenon.

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