Abstract
Three typical surface pretreatment strategies (grind, drawing, polishing) are employed to explore the influence of alloy substrate treatment on microstructure and surface performances of arc-ion plated TiN and ZrN films. The luminance and color of the films are measured by the color coordinate value of CIELab system (a color system which is defined by the International Commission on illumination). The crystal phases, morphology and microstructure are characterized and analyzed by scanning electron microscope (SEM) and X-ray powder diffraction (XRD). In addition, the anti-alkali, salt corrosion and anti-oxidation performances of films are systematically researched. The results show that the films with grinding pretreatment are more like gold color, “L” values are 77.27 cd/m2 and 80.30 cd/m2. The “b” value of TiN film is 29.96, which is the same as that of pure gold. The “a” value of ZrN film is 0.31, which is the same as pure silver. The density of TiN and ZrN films is the best, and both TiN and ZrN films were crystalline. They have the best anti-alkali and anti-oxidation performance. The films with drawing pretreatment show slant red color and have medium brightness values (74.07–76.37 cd/m2), worse compactness, obvious furrows and holes in their microstructures and worse salt corrosion and anti-oxidation performances. However, the TiN films are in amorphous states. The films with polishing pretreatment have the lowest brightness (72.66 cd/m2), gold-like color, superior compactness and best salt corrosion performance, which have a small number of holes. The TiN films with polishing pretreatment are also in amorphous state. Above all, alloy substrate pretreatment by grinding has the best gold-like color, brightness, compactness and corrosion resistance performance. This work exclusively sheds new light on surface pretreatment of alloy substrate by arc-ion plated films and also provides a reference for corrosion resistance performance of gold-like films.
Highlights
Vacuum arc-ion plating (AIP) gold-like film can make the stainless-steel alloy have its required ornamental value and operational performances [1,2]
As for the surface treatment method, we can see that the “L” values of the samples 1 and 4 are high from the “L” value curve in Figure 1, indicating that the ordinary smooth processed samples have the highest brightness value and the highest reflection intensity
[20] The results showed that the titanium nitride (TiN) film deposited on the surface of the polished technology, and the crystal grains grew the (311)and crystal
Summary
Vacuum arc-ion plating (AIP) gold-like film can make the stainless-steel alloy have its required ornamental value and operational performances [1,2]. Stainless steel alloy ornaments are favored by the market for their low cost and wide applicability. The surface film is considered as an ideal technique to isolate the alloy from the external environment and improve its performance and ornamental value [5,6]. AIP is an advanced and eco-friendly coating method [12,13]. To search for a suitable eco-friendly coating method for the ornaments, this work employs three surface pretreatment methods, and deposits titanium and zirconium nitride films on a stainless-steel alloy in AIP system. The influence of surface treatment method on the structure and anti-alkali, salt corrosion and anti-oxidation performance is systematically investigated
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
