Influence of activator type on reaction kinetics, setting time, and compressive strength of alkali-activated mineral wools

J Yliniemi,B Walkley,P Kinnunen,M Illikainen,J L Provis

doi:10.1007/s10973-020-09651-6

J Yliniemi, B Walkley + Show 3 more

Open Access

https://doi.org/10.1007/s10973-020-09651-6

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Abstract

Alkali activation is a promising utilisation route for mineral wool wastes, due to suitable chemical composition, high reactivity, and surface area. One key factor in the development of alkali-activated binders is the selection of the suitable alkali activator. Here, the effect of sodium hydroxide, sodium silicate, sodium aluminate, and sodium carbonate solution on the alkali-activation kinetics of two main types of mineral wools, stone wool and glass wool, is investigated. Setting time and compressive strength development results are presented, which are explained and discussed in the context of isothermal calorimeter data obtained at temperature of 40 °C. Sodium hydroxide and sodium silicate solutions provided fast reaction with both mineral wools, evidenced by high heat release, high early strength, and fast setting. The reaction with sodium aluminate solution took several days to initiate, but it produced high compressive strength after 28 days of curing with both mineral wools. Glass wool reacted and hardened rapidly with sodium carbonate solution, but stone wool reacted slowly with sodium carbonate and exhibited a low extent of reaction, likely due to lower extent of reaction of stone wool under less alkaline conditions. These results show that mineral wool alkali activation kinetics and binder gel formation are controlled by the activator type and highlight the importance of choosing the most appropriate activator for each desired application.

Highlights

Alkali-activated binders based on industrial side streams can represent a viable and sustainable alternative to Portland cement in many applications [1]
The fastest setting was measured for stone wool activated by NaOH solution, for which the final setting was identified after 3 h of curing
The nature of the activator plays a major part in the alkali activation process of mineral wools

Summary

Introduction

Alkali-activated binders based on industrial side streams can represent a viable and sustainable alternative to Portland cement in many applications [1]. Alkali-activated binders can be generated from a wide range of aluminosilicate precursors with differing availability, reactivity, and cost worldwide, with blast furnace slag and coal fly ash being the most common ones used [2]. Suitable raw materials (precursors and activators) should be locally available in order to minimise the costs and the environmental burden of material transportation. The precursor must be sufficiently reactive under the preparation conditions and the chemical composition should promote the formation of strong and durable binder gels. The precursor should have constant quality regarding its chemical composition and particle size distribution, eliminating extra processing steps in practical use

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