Influence of acidity and alkalinity of water environment on water stability of asphalt mixture: Phase II-microscopic erosion mechanism

Abstract

Acidity and alkalinity of water environments have been proven to influence the water stability of asphalt mixture. However, the relevant influencing mechanism still remains unclear. To fulfill this research gap, this study conducted a series of microscopic tests, aiming at unveiling the microscopic erosion mechanism of the water environment on the water stability of asphalt mixture for better moisture stability achieved. Specifically, the asphalt-aggregate interfacial transition zone (ITZ) samples were prepared by combining #70 asphalt with limestone and granite, respectively, which were then immersed in water solutions at 3 different pH levels (pH = 3.0, 7.0, and 11.0) for 7 days. The chemical composition and microstructure of the asphalt film on the surface of the ITZ samples pre and post-treatment were scrutinized using the Fourier Transform Infrared Spectroscopy (FTIR) and the Atomic Force Microscope (AFM), while the development of microcracks at the asphalt-aggregate interface were identified and traced utilizing the Scanning Electron Microscope (SEM). The test results indicate that after treatment with acidic and alkaline aqueous solutions, the asphalt film's surface is enriched with polar components such as asphaltenes, resins, and aromatic fractions. The migration of these polar components to the surface of the asphalt film reduces the adhesion between asphalt-aggregate, leading to the formation of microcracks at the asphalt-aggregate interface. The most severe crack development occurs in alkaline water environment, followed by acidic water environment. It is interestingly noted that the adhesion at the asphalt-granite interface is improved under the acidic environment. This improvement may be attributed to the covalent nature of silica, which hinders the adsorption of ions from acidic solution into the asphalt film. This hindrance effectively prevents water intrusion at the asphalt-aggregate interface, thereby reducing the adhesion loss. These findings can help elucidate the mechanism of water damage in asphalt pavement exposed to real-world conditions and enhance its water stability with effective countermeasures proposed.