Abstract
Luminescent adducts of Eu(III) tris(β-diketonate) with 1,10-phenanthroline were synthesized. The effect of the β-diketone structure on thermodynamic and photophysical properties of Eu(III) complexes was characterized. Sensitization of Eu(III) ion by various β-diketones was evaluated. The synthesized compounds are shown to form isotropic vitrified structures at room temperature allowing to produce optically isotropic vitrified films with light transmittance of over 90% and efficient luminescence. These photostable films were characterized as potential luminescent temperature sensors.
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