Abstract

Effect of organic solvents on exchange equilibria with a sulphonic acid resin. Part 1. Distribution of monovalent and divalent metal ions. The distribution coefficients of the monovalent cations sodium, cesium and silver and the divalent cations cobalt, nickel and copper between Bio-Rad AG 50W-X8 cation-exchange resin and mixtures of water with organic solvents (methanol, ethanol, n-propanol, acetone, dioxane, tetrahydrofuran, acetic acid) have been determined as a function of the composition of the aqueous—organic mixtures. The equilibrium constants k M nH (n = 1 or 2) are reported.

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