Industrial Waste-Derived Carbon Materials as Advanced Electrodes for Supercapacitors.

Abstract

Strategically upcycling industrial wastes such as petroleum coke and dye wastewater into value-added materials through scalable and economic processes is an effective way to simultaneously tackle energy and environmental issues. Doping carbon electrodes with heteroatoms proves effective in significantly enhancing electrochemical performance through alterations in electrode wettability and electrical conductivity. This work reports the use of dye wastewater as the sole dopant source to synthesize N and S co-doped petroleum coke-based activated carbon (NS-AC) by the one-step pyrolysis method. More importantly, our wastewater and petroleum coke-derived activated carbon produced on a large scale (20 kg/batch) shows a specific surface area of 2582 m2 g-1 and an energy density of about 95 Wh kg-1 in a soft-packaged full cell with 1 M TEATFB/PC as the electrolyte. The scalable production method, together with the green and sustainable process, can be easily adopted and scaled by industry without the need for complex processes and/or units, which offers a convenient and green route to produce functionalized carbons from wastes at a low cost.