Abstract

The main objective of this study was to examine the chemical characteristics, possible sources, and health risks of fine particle-bound Polycyclic Aromatic Hydrocarbons (PAHs) in the Baoshan area of Shanghai. Here, ambient particles with five-size ranges were collected during the spring and late summer of 2017. The PAHs were determined by the Gas Chromatography-Mass Spectrometry (GC-MS). Our results showed that the average mass concentration of 13 species of PAHs in spring and in late summer was 4.83 (1.88~12.1) ng/m3 and 4.27 (2.09~5.75) ng/m3 in Total Suspended Particles (TSPs), respectively. The higher PAH ratios (PM1.1/TSPs) indicated that PAHs are mainly concentrated in PM1.1, especially in late summer. The values of BaA/(BaA+CHR) were under 0.50 and IcdP/(IcdP+BghiP) were in range from 0.20 to 0.50 for TSP and PM1.1, suggesting that petroleum combustion and diesel emissions could be considered as key sources of PAHs, which tend to be associated with PM1.1. Moreover, the Principal Component Analysis (PCA) in PM1.1 identified the main PH sources, which include stationary and diesel emissions. The air mass backward trajectories and wind direction analysis showed that air masses were mainly derived from marine sources across the local industry area in late summer. Individual Carcinogenic Risk Inhalation (ILCR) was over 10−6 among the total six age groups in both of the sampling periods in TSPs, indicating the possible carcinogenic risk, especially for children and the young age group. Toxic PAHs belong to Heavy Molecular Weight (HMW) PAHs, especially Benzo[a]pyrene (BaP). Compared with PM1.1–2.0, the Combustion-Derived PAHs group (COMPAHs) and Carcinogenic PAHs (CANPAHs) were highly concentrated in PM1.1. Stationary sources, such as the developed steel industry, made a great contribution to the level of PAHs, especially in late summer.

Highlights

  • Polycyclic Aromatic Hydrocarbons (PAHs) are extensive organic contaminants comprising two or more benzene rings

  • Over 51.6% (51.6~77.2%) of PAHs in spri6nogf 15 were associated with PM2.0 (PM2.0 = PM1.1 + PM1.1–2.0) and over 57.0% (57.0~79.0%) of PAHs in late summer were associated with PM1.1, which showed that the PAHs mainly associate woiftPhAfiHnes pinarlatitcelessuamnmd ewrewreerheigahsslyoccioantecdenwtriathtePdMin1.t1h,ewfhinicehpsahrtoiwclesdotfhPatMth1.1einPAlaHtessmumain- ly masesro. ciate with fine particles and were highly concentrated in the fine particles of PM1.1 in late summer

  • Particle-bound PAHs in the ambient Baoshan area of Shanghai were first measured for their chemical characterization, possible sources, and toxic evaluation during the spring and late summer

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Summary

Introduction

Polycyclic Aromatic Hydrocarbons (PAHs) are extensive organic contaminants comprising two or more benzene rings. It has already been reported that the species of water-soluble inorganic ions in ambient particles could increase the solubility of toxic organic compounds, such as PAHs, by acting as surface-active agents [4–7]. With their low vapor pressure, PAHs with heavier molecular weights could be absorbed by the fine inhalable particles in the atmosphere. This has indicated that PAH compounds with 5–6 benzene rings are usually associated with PM2.0 [6,8]. PAHs are more notably carcinogenic to humans than individual hydrocarbons [12–14]

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