Abstract
The indium(III) complexes containing 4,6-di-tert-butyl-N-(2,6-di-iso-propyl-phenyl)-o-iminobenzoquinone (imQ) in dianion o-amidophenolate (AP) (1) or radical-anion o-iminobenzosemiquinolate (imSQ) (3) form and iodide ligands (one in the case of 1 or two in the case of 3) have been obtained in the presence of donor agent (tetramethylethylenediamine (TMED)). The 4,6-di-tert-butyl-N-(2,6-di-iso-propyl-phenyl)-o-amidophenolate-ethyl-indium(III) (2) was obtained by the exchange reaction of disodium o-amidophenolate (APNa2) with I2InEt. Structures of complexes 1, 2 and 3 were determined by X-ray diffraction analysis.
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