Indium/Cu(II)-mediated one-pot synthesis of unsymmetrical diaryl amines from aryl boronic acids and azides

B.V Subba Reddy,N Sivasankar Reddy,Y Vikram Reddy,Y Jayasudhan Reddy

doi:10.1016/j.tetlet.2011.03.022

Indium/Cu(II)-mediated one-pot synthesis of unsymmetrical diaryl amines from aryl boronic acids and azides

B.V Subba Reddy, N Sivasankar Reddy + Show 2 more

https://doi.org/10.1016/j.tetlet.2011.03.022

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Journal: Tetrahedron Letters	Publication Date: Mar 17, 2011
Citations: 20

Affiliation: Indian Institute of Chemical Technology

#Synthesis Of Diaryl Amines #Aryl Azides + Show 8 more

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Abstract

Aryl azides react smoothly with aryl boronic acids in the presence of indium metal in methanol to furnish a variety of unsymmetrical diaryl amines in good yields. This is the first report on the synthesis of diaryl amines from the cross coupling of aryl azides with aryl boronic acids via N-arylation.

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