Abstract
Indium-mediated allylation of α-chlorocarbonyl compounds with various allyl bromides in aqueous media gave the corresponding homoallylic chlorohydrins, which could be transformed into the corresponding epoxides in the presence of a base. These reactions were strongly dependent upon both the substituents at the carbon bearing chlorine and the allyl bromides used.
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More From: Journal of the Chemical Society, Perkin Transactions 1
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