Abstract
The coumarin-thiol-based colorimetric and fluorimetric chemosensor (E)-7-(diethylamino)-3-((2-mercaptophenylimino)methyl)-2H-chromen-2-one 1a was designed, synthesized, and evaluated for anion detection through the metal displacement mechanism. Chemosensor 1a exhibited a high sensitivity and selectivity to Hg2+ ion detection in HEPES-buffered solution [20 mM, 3:7 CH3CN/H2O (v/v), pH 7.0] with a 1:1 binding stoichiometry and a 5.549 × 105 M–1 binding constant. The fluorescence intensity of chemosensor 1a was selectively quenched by Hg2+, and an obvious color change from yellowish green to orange was observed by the naked eye. Moreover, a solution of the in situ generated 1a + Hg2+ complex displayed a high selectivity to CN– through the Hg2+ displacement approach. The gradual addition of CN– to the resultant solution of the 1a + Hg2+ complex induced its fluorescence recovery with a detection limit of 31 nM. This reversibility in fluorescence suggests the promising applicability of chemosensor 1a as an “on–o...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.