Abstract

Partially reduced SnO2 was prepared by using NaBH4 as reducer under room temperature. After NaBH4 treatment, the oxygen vacancy density of SnO2 was increased greatly. X-ray photoelectron spectroscopy, photoluminescence and electron paramagnetic resonance indicates that the obtained materials are characteristic of a high concentration of oxygen vacancies. Owing to increased oxygen vacancy concentration, these materials showed significantly high gas-sensing response to ethanol. Compared with the ethanol-sensing response value of 36.9 for pristine SnO2 towards 300 ppm ethanol, the response value for the partially reduced SnO2 is 120.3. This ethanol-sensing response enhancement may be attributed to the fact that the increased surface oxygen vacancy facilitates oxygen adsorption, and promotes chemical reaction on the surface.

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