Abstract

Intense electrochemiluminescence (ECL) was observed from sandwich cells. The cell structure is as follows: F-doped (2,-bipyridyl)ruthenium(II) complex in acetonitrile/ F-doped . Intense ECL was observed only when negative cell voltage was applied to nanoporous electrodes. The ECL increased with an increase in the surface area of porous layers. ECL increase was observed for porous ZnO electrodes, but not for porous electrodes. It was concluded that increases in ECL are associated with the formation of in porous electrodes and the process taking place after reduction of which occurs in the porous electrodes.

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