Abstract
Incoherent elastic neutron scattering measurements are performed on thin (75 to 1015 A) polycarbonate films supported on Si wafers. We find that the mean-square atomic displacement <u(2)> is diminished by thin film confinement. For film thicknesses comparable to the unperturbed dimensions of the macromolecule, we observe two characteristic crossover temperatures in <u(2)> as a function of temperature T, one above and the other below the bulk T(g). Furthermore, the harmonic force constant kappa, defined by the low temperature dependence of <u(2)> (i.e., kappa approximately k(B)T/<u(2)>), increases as the film thickness decreases. These observations suggest that the atoms are more strongly localized in the thin supported films.
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