Abstract

Trapping of migrating incoherent electronic excitation in dynamically disordered systems has been studied by the dynamic disorder hopping (DDH) method. The central point is the calculation of the DDH averaged number of visited sites 〈 S( t)〉 which determines the donor excitation survival probability 〈 P D ( t)〉. The method presented is applied to migrative excitation trapping (MET) (i) along a vinyl chain of chromophores and (ii) in polymer fractals.

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