Incineration of carbon nanomaterials with sodium chloride as a potential source of PCDD/Fs and PCBs

Abstract

The incineration of waste carbon nanomaterials will become an inevitable waste management strategy following the disposal of products containing carbon nanomaterials. We investigated the formation of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) and polychlorinated biphenyls (PCBs) during the incineration of selected carbon nanomaterials [fullerene (C60), single-walled carbon nanotubes (SWNTs), and graphene], with sodium chloride and trace copper at 850 °C in air using a laboratory-scale electric furnace. Most PCDD/Fs and PCBs were concentrated in particulate fly ash post-incineration, and in low-temperature zones in the furnace (54–670 °C). Notably, C60 had a specific thermal behavior leading to the formation of high concentrations of high chlorinated PCDD/Fs and toxic 2,3,7,8-tetra-CDD/F (2,3,7,8-T4CDD/F). SWNTs had a lower potential to generate such compounds than C60, but had a higher potential than graphene and graphite. Temperature, solid/gas phases, chlorine sources, and the thermal stability of carbon nanomaterials were the key controlling factors. There is a need to consider the generation of PCDD/Fs and PCBs during the incineration of waste streams containing carbon nanomaterials.