Abstract
In situ XRD reaction device combined with the online gas chromatography was used to study the oxidation behavior of the effect of H2O content (4.36%, 1.68%, 0.56%) on the phase and Fischer-Tropsch synthesis (FTS) performance of the single phase Fe5C2. The results show that the oxidation rate of the Fe5C2 phase increases with the increase of the content of injected H2O. Meanwhile, the particle size of Fe5C2 phase decreases and more active sites exposes during the H2O oxidation, resulting in the increase of the FTS activity. Furthermore, the FTS activity increases with the increase of the oxidation times, but the selectivity of CH4 increases and the C5+ selectivity decreases gradually.
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