In-situ synthesis of metal nanoparticle embedded soft hybrid materials via eco-benign approach

Abstract

Abstract The unique optical and electronic properties of metal nanoparticles and tunable properties of the organic templates encourage the scientific community to generate metal nanoparticle embedded soft hybrid materials for various novel utilities. Here, we discuss the in-situ synthesis of metal nanoparticle embedded soft hybrid materials via eco-benign approach which exclude the use of toxic reducing/capping agents or toxic reaction media. In this protocol, the gel matrix composed of benign organic templates act as reducing as well as stabilizing agent for the in-situ generation and stabilization of metal nanoparticles. As the incorporation of metal salts (as nanoparticle precursor) in the gel medium is required in this process, in most of the cases aqueous media were used for the generation of metal nanoparticle embedded soft hybrid materials. This discussion includes interesting findings from our laboratory where hybrid gel matrix composed of renewable chemicals was utilized for the in-situ synthesis of palladium nanoparticle embedded soft trihybrid material. The hybrid gel matrix rich in polyphenols/flavonoids was exploited to generate palladium nanoparticle embedded trihybrid gel through in-situ reduction of doped Pd (II) salts to stable PdNPs. The xerogel of this trihybrid material was utilized as recyclable heterogeneous catalyst for C-C coupling reaction in air under phosphene free condition and reduction reaction.