In situ synthesis of magnesium-doped hydroxyapatite aerogel for highly efficient U(VI) separation with ultra high adsorption capacity and excellent recyclability

Abstract

Mg-doped HAP aerogel (MHAPA) was firstly in situ prepared via freeze-drying-calcination technology to capture U(VI). The U(VI) removal capacity by MHAPA even arrived 2685.6 mg g−1, which was about 2 times over purchased HAP, illustrating that the incorporation of Mg ions could greatly enhance the U(VI) removal capacity. Compared with HAP, MHAPA also showed better anti-ion interference ability and dynamic removal performances. In comparison with other HAP-based adsorbents, MHAPA possessed good recyclability and its desorption rate was up to 93.4% in the first cycle. The excellent U(VI) removal performances of MHAPA might be owing to its low crystallinity and grain size, fast ion exchange rate and partial ionization under acidic conditions, which would accelerate the process of electrostatic attraction, ion-exchange, and complexation to immobilize U(VI). To sum up, the prepared MHAPA was expected to be an environmentally friendly, recyclable and effective adsorbent to immobilize U(VI) in actual wastewater.