In-situ synthesis of FeS/N, S co-doped carbon composite with electrolyte-electrode synergy for rapid sodium storage

Abstract

Pyrrhotite (FeS) is extensively investigated as the anode for low-cost sodium-ion batteries (SIBs) due to their natural abundance and high theoretical capacity. However, it suffers from significant volume expansion and poor conductivity. These problems can be alleviated by promoting sodium-ion transport and introducing carbonaceous materials. Here, FeS decorated on N, S co-doped carbon (FeS/NC) is constructed through a facile and scalable strategy, which is the best of both worlds. Moreover, to give full play to the role of the optimized electrode, ether-based and ester-based electrolytes are used for matching. Reassuringly, the FeS/NC composite displays a reversible specific capacity of 387 mAh g−1 after 1000 cycles at 5A g−1 in dimethyl ether electrolyte. The even distribution of FeS nanoparticles on the ordered framework of carbon guarantees a fast electron/Na-ion transport channel, and the reaction kinetics can be further accelerated in the dimethyl ether (DME) electrolyte, ensuring the excellent rate capability and cycling performance of FeS/NC electrodes for sodium-ion storage. This finding not only provides a reference for the introduction of carbon via in-situ growth protocol, but also demonstrates the necessity for electrolyte–electrode synergy in realizing efficient sodium-ion storage.