In-situ synthesis of copper phytate-hierarchically porous MOF-199 hybrid in wood towards multifunctional flame-retardant wood composite

Abstract

The modern society pays growing attention on global environmental issues, public safety, and individual health, which highlights the necessity of exploring sustainable, energy-saving, flame-retardant, and anti-mildew materials for building applications. Herein, by in-situ preparing copper phytate-hierarchically porous MOF-199 hybrid (PCuM) in natural wood (W) via simple phytate induced defect engineering strategy, we reported a multifunctional low fire-hazard wood composite (PCuM-W). The phytate anion not only acted as a modulator to generate hierarchical porosity in MOF-199, but also offered high flame retardancy due to its six phosphorus groups. The copper phytate anchored on the cell wall exhibited charring and graphitizing effects and enhanced the flame retardancy and smoke suppression performance of wood. By pyrolysis, a hierarchically porous MOF-199-derived carbon formed and offered a considerably enhanced catalytic activity towards the conversion of CO. With a weight percent gain of only 13.5%, the fire growth index, total smoke production, and maximum CO production rate of PCuM-W were 74.2%, 85.4%, and 33.3% lower than that of W, respectively, showing outstanding fire-hazard-reducing efficiency that surpassed most of its counterparts. Furthermore, due to the hierarchical porosity and antimicrobial property of PCuM, PCuM-W showed excellent moisture-buffering ability and mildew resistance. This work brings guidelines for fabricating hierarchically porous MOFs to realize multifunctional materials via phytate induced defect engineering.