In situ synthesis of binary cobalt–ruthenium nanofiber alloy counter electrode for electrolyte-free cadmium sulfide quantum dot solar cells

Abstract

A facile, low-cost and low-temperature fabrication approach of counter electrode is essential for pursuing robust photovoltaic devices. Herein, we develop a hydrothermal in situ growth of Cobalt–Ruthenium (Co–Ru) alloy nanofiber electrode for quantum dot solar cell (QDSC) applications. Colloidal CdS QDs with tunable absorption band edge are synthesized and used as light absorber. After optimizing the QDs with the highest photoluminescence quantum yield accompanied by considerable solar light absorption ability, QDSC based on Co–Ru alloy electrode delivers a much higher power conversion efficiency than its counterparts, i.e., either pure Co or Ru metal electrodes. In detail, Co–Ru alloy electrode exhibits high specific area, excellent electrical behavior, intimate interface contact, and good stability, thus leading to notable improved device performances. The impressive robust function of Co–Ru alloy with simple manufacturing procedure highlights its potential applications in robust QDSCs.