Abstract
Abstract Codeposition of phosphorus with nickel on an Ni–Ag alloy electrode has been investigated by means of in situ surface enhanced Raman spectroscopy (SERS) to obtain information about the phosphorus incorporation mechanism during electrodeposition of Ni–P alloys. The experimental results showed that in the solution without NiSO4, hypophosphite was reduced only to a Ni–phosphine compound, while in the case where NiSO4 coexisted in the solution, the Ni–phosphine compound, as an intermediate, was oxidized by Ni2+ to elemental phosphorus in alloys with nickel acting as the catalyst.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
