Abstract

A dense V2AlC ceramic was synthesized by an in situ reaction/hot pressing method using V, Al, and C powders as starting materials. The reaction path was investigated. It was found that V2AlC was produced by a reaction between Al8V5 and C. Single ‐phase V2AlC could be prepared using the optimized molar ratio of V:Al:C=2:1.2:0.9. The grain sizes of as‐prepared V2AlC samples were temperature dependent. On increasing the temperature from 1400° to 1700°C, the mean grain size of V2AlC increased from 49 μm in length and 19 μm in width to 405 μm in length and 106 μm in width. The V2AlC sample sintered at 1500°C exhibited the highest flexural strength of 289 MPa and a fracture toughness of 5.7 MPa·m1/2, while the V2AlC sample prepared at 1400°C showed the highest compressive strength of 742 MPa. The sample sintered at 1700°C possessed the highest damage tolerance. Additionally, V2AlC could retain a high degree of Young's modulus up to 1200°C. Below 800°C, V2AlC showed excellent thermal shock resistance.

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