In situ Raman spectroscopy studies of catalysts

Abstract

In situ Raman spectroscopy is rapidly becoming a very popular catalyst characterization method because Raman cells are being designed that can combine in situ molecular characterization studies with simultaneous fundamental quantitative kinetic studies. The dynamic nature of catalyst surfaces requires that both sets of information be obtained for a complete fundamental understanding of catalytic phenomena under practical reaction conditions. Several examples are chosen to highlight the capabilities of in situ Raman spectroscopy to problems in heterogeneous catalysis: the structural determination of the number of terminal M=O bonds in surface metal oxide species that are present in supported metal oxide catalysts; structural transformations of the MoO3/SiO2 and MoO3/TiO2 supported metal oxide catalysts under various environmental conditions, which contrast the markedly different oxide–oxide interactions in these two catalytic systems; the location and relative reactivity of the different surface M–OCH3 intermediates present during CH3OH oxidation over V2O5/SiO2 catalysts; the different types of atomic oxygen species present in metallic silver catalysts and their role during CH3OH oxidation to H2CO and C2H4 epoxidation to C2H4O; and information about the oxidized and reduced surface metal oxide species, isolated as well as polymerized species, present in supported metal oxide catalysts during reaction conditions. In summary, in situ Raman spectroscopy is a very powerful catalyst characterization technique because it can provide fundamental molecular‐level information about catalyst surface structure and reactive surface intermediates under practical reaction conditions.