In Situ Preparation of rGO-Cement Using Thermal Reduction Method and Performance Study.

Abstract

In this study, the combination of freeze-drying and high-temperature thermal reduction methods was employed to in situ prepare reduced graphene oxide (rGO)-Cement based on graphene oxide (GO)-Cement. The electrical conductivity and mechanical properties of the rGO-Cement were investigated. Microscopic analysis methods such as Raman spectra, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) were used to confirm the successful transformation of GO-Cement to rGO-Cement. The research results demonstrated that with an increase in rGO content, the electrical resistivity of the rGO-Cement decreased first and then increased, reaching a percolation threshold at the dosage of 0.7 wt.%. The compressive strength and flexural strength of the rGO-Cement increased first and then decreased. The optimal dosage of rGO was 0.7%. The in situ preparation of rGO-Cement using the thermal reduction method holds a great potential for various applications, providing new ideas and methods for the modification and enhancement of cement materials.