Abstract
Redox affected pumice tuff was used to investigate the changes of pore properties due to oxidation and its possible consequences to adsorption of nuclides on it. Porosity and pore size distribution were analyzed by mercury injection technique and scanning electron microscopy. Batch experiment was carried out with 1 cm3 block shaped intact pumice tuff samples to determine adsorption coefficient, Kd at several pH, ionic strength and initial nuclide concentrations of stable cesium (133Cs). Pore area, surface area and specific surface area were determined from pore size distribution data before and after adsorption experiment and later compared between fresh and oxidized samples. The results showed that reduction of less than 0.33 μm size micro pores due to oxidation is mainly responsible for reducing surface areas, eventually reducing the sorption quantity. Influence of pore properties became negligible in redox affected pumice tuff indicating inverse relation of oxidation phenomena with adsorption coefficients values.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
