In Situ One-Pot Synthesis of C-Decorated and Cl-Doped Sea-Urchin-like Rutile Titanium Dioxide with Highly Efficient Visible-Light Photocatalytic Activity

Abstract

Titanium dioxide (TiO2) that offers high light-harvesting capacity and efficient charge separation holds great promise in photocatalysis. In this work, an in situ one-pot hydrothermal synthesis was explored to prepare a C-decorated and Cl-doped sea-urchin-like rutile TiO2 (Cl-TiO2/C). The growth of sea-urchin-like 3D hierarchical nanostructures was governed by a mechanism of nucleation and nuclei growth-dissolution-recrystallization growth from time-dependent morphology evolution. The crystal morphology and the content of Cl and C could be controlled by the volume ratio of HCl to TBOT. Systematic studies indicated that the 0.4Cl-TiO2/C sample (the volume ratio of HCl to TBOT was 0.4) exhibited the highest visible-light photocatalytic activity for the degradation of rhodamine B, with kinetic rate constant (k) of 0.0221 min-1, being 6.5 and 3.75 times higher than that of TiO2 and Cl-TiO2. The enhanced photocatalytic performance could be attributed to the high charge separation and transfer efficiency induced by Cl-doping and C decoration and the excellent light-harvesting capacity caused by its sea-urchin-like nanostructure. Moreover, the 0.4Cl-TiO2/C sample exhibited good reusability and excellent structural stability for five cycles. This facile one-pot approach provides new insight for the preparation of a TiO2-based photocatalyst with excellent photocatalytic performance for potential application in practical wastewater treatment.