In Situ Observation of Phase Transformation and Structure Evolution of a 12 pct Cr Ferritic Stainless Steel

Abstract

This work focuses on an in situ observation of phase transformation of a 12 pct Cr ferritic stainless steel using high-temperature laser scanning confocal microscopy. α→γ→δ phase transformation temperatures are determined to be approximately 1073 K and 1423 K (800 °C and 1150 °C), respectively. The onset of phase transformation is found to occur at grain boundaries. When the temperature is beyond 1518 K (1245 °C), the grain growth rate suddenly becomes very high, and the grain growth is related to the self-organizing of adjacent grains. δ→γ phase transformation has been mostly restrained when cooling rates are in the range of 22.4 K/s to 13.3 K/s (22.4 °C/s to 13.3 °C/s) except for at grain boundaries. Martensitic phase transformation, rather than γ→α phase transformation, occurs when the cooling rates are in the range of 8.5 K/s to 2.2 K/s (8.5 °C/s to 2.2 °C/s). The starting temperature of martensitic phase transformation is approximately 697 K to 728 K (424 °C to 455 °C) for specimens heated to 1373 K (1100 °C) (i.e.,γ phase field), which is 50 K to 100 K (50 °C to 100 °C) higher than that of specimens heated to 1723 K (1450 °C) (i.e.,δ phase field). Many bulges remain on the surfaces of the specimen heated to 1723 K (1450 °C), and their formation mechanism is analyzed.