Abstract

Starting from the binuclear complex [RhCl(CO 2)] 2 in the presence of the phosphines L=PMe 3, PMe 2Ph, and PMePh 2 various mononuclear dihydrides of the type Rh(H) 2(SnCl 3)L 3 have been obtained upon the addition of parahydrogen, and their 1H NMR spectra have been investigated using Para Hydrogen Induced Polarization (PHIP).

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