Abstract
AbstractA linearly polymerizing and network forming epoxy‐amine system, DGEBA‐aniline and DGEBA‐MDA, respectively, will be modified with 20 wt% and 50 wt% of a high‐Tg thermoplastic poly(ether sulphone) (Tg=223°C), respectively, both showing LCST‐type demixing behavior. Reaction‐induced phase separation (RIPS) in these modified systems is studied using Modulated Temperature DSC (MTDSC) as an in situ tool. Phase separation in the linear system can be probed by vitrification of the PES‐rich phase, occurring at a higher conversion than the actual cloud point from light scattering measurements. The negative slope of the cloud point curve in a temperature‐conversion‐transformation diagram unambiguously shows the LCST‐type demixing behavior of this system, while the relation between the composition/glass transition of the PES‐rich phase and the cure temperature is responsible for the positive slope of its vitrification line. Phase separation in the network forming system appears as reactivity increases at the cloud point due to the concentration of reactive groups. Different mixture compositions alter the ratio between the rate of phase separation and the rate of reaction, greatly affecting the morphology. Information about this in situ developed structure can be obtained from the heat capacity evolutions in non‐isothermal post‐cures.
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