Abstract
The adsorption of a charged thiol (HSC10COO-) on gold from its aqueous solutions of different concentration was monitored in situ by probing the surface charge. This was accomplished by measuring the interfacial forces between a modified (with a negatively charged silica sphere) tip of an atomic force microscope and the thiol-adsorbed gold surface as a function of adsorption time. The surface charge and potential were then deduced from the force data. If a Langmuir rate law is employed to fit the overall surface coverage vs time data, average observed adsorption rate constants of 0.045 ± 0.005 (0.5 mM) and 0.020 ± 0.003 (0.05 mM) min-1 were obtained and were dependent on thiol concentration. The self-assembly process was a two-step process, an initial fast step followed by a slow step.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
