Abstract
Fibrous morphology and nano-crystalline nature of the anodically deposited manganese oxide were confirmed by a transmission electron microscope (TEM). The oxide electrode exhibited an ideal capacitive behavior as indicated by cyclic voltammetry (CV). In order to explore the energy storage mechanism, variation of electronic and structural aspects of the manganese oxide induced by changing the applied potential was studied in situ in aqueous 2 M KCl by Mn K-edge X-ray absorption spectroscopy (XAS). Position shift of the adsorption edge, toward higher energy during oxidation and backward lower energy during reduction, was clearly recognized. The experimental results directly proved for the first time that the pseudo-capacitance of the manganese oxide was attributed to its continuous and reversible faradic redox reaction during the charge–discharge process.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
