In situ growth of SnO 2 nanowires on the surface of Au-coated Sn grains using water-assisted chemical vapor deposition

Abstract

SnO 2 nanowires (NWs) have been directly synthesized in high-yield on the surface of Au-coated Sn grains using a water-assisted chemical vapor deposition (CVD) method. The Au-coated Sn grains served themselves as both the Sn source, which reacted with H 2O vapor at 700–800 °C under the flow of high purity N 2 carrier, and the substrate for the growth of the SnO 2 NWs. The synthesized SnO 2 NWs were systematically studied using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The single-crystalline SnO 2 NWs are about 100–150 μm in length and 16–60 nm in diameter, which can be tuned by simply adjusting the CVD temperature. A possible formation mechanism of SnO 2 NWs was proposed and discussed. Gas sensors based on SnO 2 NWs prepared at 800 °C exhibited excellent sensing performance, characterized with excellent selectivity and fast response time to ethanol vapor and H 2S gas operating at 320 °C.