In situ generation of nickel/carbon catalysts by partial gasification of coal char and application for methane decomposition

Abstract

Catalytic methane decomposition (CMD) has a good potential to develop environmentally friendly hydrogen economy, and the catalyst plays a vital role on its applications. In this work, a novel strategy was proposed to fabricate efficient and effective nickel/carbon catalysts for CMD by introducing some additional nickel and K2CO3 into partial steam gasification of coal char. The gasification process is conducive to in situ synthesize nickel crystallites with high reduction degree (the value of Ni0/(Ni0+Ni2+) up to 76%–81%) on the catalyst surface, and it is competent for co-generation of hydrogen-rich gas and nickel/carbon hybrids with large surface areas (around 86–149 m2/g after washing off the residual potassium salts). The nickel/carbon hybrid as the gasification residue could serve as the catalyst for CMD, showing high and stable methane conversion (up to 80%–87%) at 850 °C. It is observed that co-production of hydrogen and filamentous carbons can be achieved in the 600-min process of CMD, thanks to the positive effect of K2CO3 on formation and activity improvement of the nickel/carbon catalyst.