Abstract

Abstract Bimetallic Au–Pd clusters were successfully elaborated by selective deposition over citrate-functionalized TiO2 nanocrystallites. Anisotropic gold nanoparticles are obtained by adjusting the Pd/Au ratio. An original method to generate “in situ” H2O2 from formic acid and O2 is discussed and evaluated in the selective oxidation of benzyl alcohol as a model reaction.

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